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iTSSe

TSS

A D V A N C E D M A T E R I A L S & P R O C E S S E S | J U L Y / A U G U S T 2 0 1 6

4 2

iTSSe

TSS

12

JTST

HIGHLIGHTS

torch sprayed an Inconel coating on the foil’s surface. A burner

test rig was built to produce hot combustion gases that flowed

over the exposed face of the heat exchanger. Cool air flowed

through the foam heat exchanger at rates of up to 200 SLPM.

Surface temperature and air inlet/exit temperature were mea-

sured. Heat transfer to air flow through the foam was signifi-

cantly higher for the thermal sprayed heat exchangers than

for the brazed heat exchangers. On average, thermal sprayed

heat exchangers show 36% higher heat transfer than conven-

tionally brazed foam heat exchangers. At low flow rates, the

convective resistance is large (~4 × 10

−2

m

2

K/W), and the effect of thermal con-

tact resistance is negligible. At higher flow

rates, the convective resistance decreases

(~2 × 10

−3

m

2

K/W), and the lower contact

resistance of the thermally sprayed heat

exchanger provides better performance

than the brazed heat exchangers.

PLASMA-SPRAYED

HYDROXYLAPATITE-BASED

COATINGS: CHEMICAL,

MECHANICAL, MICROSTRUC-

TURAL, AND BIOMEDICAL

PROPERTIES

Robert B. Heimann

The salient properties and func-

tions of hydroxylapatite (HA)-based plas-

ma-sprayed coatings, including the effect

on biomedical efficacy of coating thick-

ness, phase composition and distribution,

amorphicity and crystallinity, porosity

and surface roughness, cohesion and

adhesion, micro- and nano-structured

surface morphology, and residual coating

stresses are discussed. In addition, details

of the thermal alteration that hydroxylap-

atite particles undergo in the extremely

hot plasma jet that leads to dehydroxyl-

ated phases such as oxyhydroxylapatite

(OHA) and oxyapatite (OA) are discussed.

Thermal decomposition products such

as tri-(TCP) and tetracalcium phosphates

(TTCP), and quenched phases such as

amorphous calcium phosphate (ACP), are

also discussed. The article further explains

the role of amorphous calcium phos-

phate during the in vitro interaction of as-

deposited coatings with simulated body

fluid resembling the composition of extra-

cellular fluid (ECF) as well as the in vivo

responses of coatings to the extracellu-

lar fluid and the host tissue, respectively.

Fig. 3. —

Test rig.

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