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A D V A N C E D

M A T E R I A L S

&

P R O C E S S E S | J U L Y / A U G U S T

2 0 1 6

2 3

strength and ductility are possible, as

seen in Fig. 3. This article focuses on

one sheet steel design produced from

example Alloy 1.

TARGETED MICROSTRUCTURE

FORMATION

The properties of each alloy

depend on the chemistry as well as spe-

cific steel mill processing parameters.

For example, Alloy 1 has a proprietary

iron-based alloy chemistry that, when

processed, results in ultimate tensile

strength of roughly 1200 MPa with aver-

age elongation of 50% (Fig. 3) as seen in

the tensile stress-stain curve in Fig. 4.

The two microconstituents that

comprise these alloys enhance prop-

erties through their ability to act syn-

ergistically.

Microconstituent A

consists

of micron-sized austenitic grains with

dislocation networks and nanopre-

cipitates. This constituent, with its

larger grain sizes, mainly supports high

ductility in the final steel with strength-

ening through nanoprecipitation.

The second component,

microcon-

stituent B,

is comprised of nanoscale

ferritic grains with nanoprecipitates

that form during deformation. This pro-

vides strength due to the combination

of nanoscale grain sizes and nanopre-

cipitation with both the austenite and

transformed ferrite contributing to

ductility. These two components (~50%

each) in the

mixed microconstituent

structure of Alloy 1 can be seen in Fig. 5.

PROCESSING AND

FINAL PROPERTIES

The way in which industrial steel is

made is a key factor in the mixed micro-

constituent structure formation in the

final sheet. In the steel mill, an alloy is

continuously cast into slabs using stan-

dard high-throughput mill equipment.

The cast alloy then solidifies into den-

dritic structures with austenite grains

and interdendritic pinning phases con-

taining nanoprecipitates (Fig. 6). The

properties at this point demonstrate

tensile strength of around 600 MPa and

elongation below 15%.

In the next stage, slabs are heated

in the tunnel furnace to within 50-100°C

of the melting point. Hot rolling the

slab reduces thickness and forms a

hot band, which is then air cooled and

spooled into a coil. The hot-band mate-

rial structure is seen in the second stage

of Fig. 6 (the nanomodal structure). The

nanomodal structure sees significant

structural refinement taking place as

grain size is reduced, leading to signif-

icant property improvement. At this

stage, the hot band material features

the required tensile strength of about

1200 MPa and elongation over 40%.

Next comes cold rolling, where

material strength is further developed.

Cold rolling is done in multiple passes,

depending on the starting thickness

of the hot band and desired thick-

ness of the cold rolled sheet. The high

strength nanomodal structure of the

resulting cold rolled sheet occurs due

to extensive deformation through dis-

location mechanisms with phase trans-

formation. The structure consists of

transformed nanoscale ferrite grains,

retained austenite, and nanoprecipi-

tates. The effect of this phase transfor-

mation is demonstrated by increased

strength, in the case of Alloy 1 to over

1600 MPa with an associated reduction

in elongation to about 15%.

At this point, the material must be

annealed to restore ductility before it

can be used in an automotive structural

Fig. 2 —

WorldAutoSteel banana plot with target properties for third generation AHSS.

Fig. 3 —

Modified WorldAutoSteel banana plot with property ranges achievable through a new

approach to developing third generation AHSS.

Fig. 4 —

Tensile stress-strain curve for Alloy 1

and view of corresponding ASTM E8 tensile

specimens before and after deformation.

Elongation, %

Tensile strength, MPa

Elongation, %

Tensile strength, MPa

Engineering stress, MPa

Engineering strain, %