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A D V A N C E D

M A T E R I A L S

&

P R O C E S S E S |

M A R C H

2 0 1 5

1 1

As an alternative, NIST researchers

used electron backscatter diffraction

(EBSD) to read, in the crystal structure

pattern, imprints on steel that had been

removed by polishing. The more perfect

the crystal structure, the stronger and

clearer the pattern. Software can then

calculate the pattern quality to reveal

crystal damage; areas with more dam-

age produce lower quality patterns.

Ordinary SEM imaging meth-

ods reveal very faint outlines of the X

stamps in the metal grains, whereas

pattern quality mapping shows the out-

lines more clearly. The latter technique

is significantly more sensitive to small

amounts of crystal lattice damage.

While the method is still experimental,

it holds a lot of promise, say research-

ers.

nist.gov.

CHARACTERIZING

SUPERHYDROPHOBICITY

Scientists recently discovered that

inherently water repellent surfaces can

be made superhydrophobic by pattern-

ing themwith micro or nanoscale struc-

tures. On such surfaces, water droplets

can be either suspended across neigh-

boring protrusions or impaled between

them. The transition between these

two states as well as the effect of mi-

crostructures on vapor condensation

have been investigated, but few com-

putational studies have explored how

droplets initially form by condensation

from vapor.

Now, Weiqing Ren of the A*STAR

Institute of High Performance Com-

puting, Singapore, and Yunzhi Li of the

National University of Singapore have

systematically analyzed how micropil-

lars on a hydrophobic surface affect the

condensation of water vapor. They used

a powerful computational technique

known as the string method, which Ren

developed in a previous study.

Ren and Li used this technique to

investigate the effect of parameters such

as the height and spacing of micropillars

and the supersaturation and intrinsic

wettability of the surface on the con-

densation process. They discovered that

both the pathway and configuration of

the initial nucleus from which droplets

form—the

critical nucleus

―depend on

the geometry of the surface patterns. In

particular, they found that for tall, close-

ly spaced pillars on a surface with low

supersaturation and low wettability, the

critical nucleus prefers the suspended

state, whereas for the opposite case it

prefers the impaled state. By generat-

ing a phase diagram, critical values of

the geometrical parameters at which

the configuration of the critical nucleus

changes from the suspended state to the

impaled state can be determined.

www. ihpc.a-star.edu.sg

.

Superhydrophobic surfaces hold promise

for industrial applications as well as

self-cleaning, defrosting, and anti-icing

surfaces. Courtesy of Yurok Aleksan-

drovich/iStock/Thinkstock.

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